The Bochet group
Organic synthesis and photochemistry

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Department of chemistry
Chemin du Musee 9
CH-1700 Fribourg
Switzerland
Tel.: +41-(0)26-300 8758
Fax: +41-(0)26-300 9738
christian.bochet (at) unifr.ch

 

 
Publications

- T. Solomek, S. Mercier, T. Bally, C.G. Bochet, Photolysis of ortho-nitrobenzylic derivatives: the importance of the leaving group, 2012, in press.

- J.L. Débieux, C.G. Bochet, The all-photochemical synthesis of an OGP(10-14) precursor, Chem. Sci. 2011, in press.

- C.G. Bochet, A. Blanc, Photolabile protecting groups in organic synthesis, in 2010 CRC Handbook of photochemistry and photobiology, A. Griesbeck, M. Oelgemoeller, Eds, Taylor and Francis 2011, in press.

- N. Charbonnet, E. Riguet, C. G. Bochet, Singlet oxygen-induced rearrangement of furan derivatives, Synlett, 2011, 2231-2233.

- V. San Miguel Arnanz, C. G. Bochet, A. del Campo, Wavelength selective caged surfaces: how many functional levels are possible? J. Am. Chem. Soc. 2011, 133, 5380-5388.

- U. Streit, C. G. Bochet, The arene-alkene photocycloaddition, Beilstein Journal of Organic Chemistry, 2011, 7, 525-542.

- H. Haning, C.G. Mañas, V. Paddock, C.G. Bochet, A.J.P. White, G. Bernardinelli, I. Mann, W. Oppolzer, A.C. Spivey, Total Synthesis of the Amaryllicaceae Alkaloid Clivonine, Org. Biomol. Chem. 2011, 9, 2809-2820.

-  T. Jack, J. Simonin, S. Singhanat, C. G. Bochet, “Unconventional Methods in Organic Synthesis”, 41th CUSO Summer School in Organic Chemistry. Chimia 2011, 65, 97-99.

- C.G. Mañas, V. Paddock, C.G. Bochet, A.C. Spivey, A.J.P. White, I. Mann, W. Oppolzer, Total Synthesis of the Lycorenine-type Amaryllicaceae Alkaloid (+/-)-Clivonine via a Biomimetic Ring-switch from a Lycorine-type Progenitor, J. Am. Chem. Soc. 2010, 132, 5176-5178.

- J.L. Débieux, C.G. Bochet, Photoinduced acyl transfer, J. Phys. Org. Chem. 2010, 23, 272-282.

- C.G. Bochet, Hard work and light experience: early steps in photochemistry, Chimia 2009, 63, 872-874

- C.G. Bochet, T. Draper, B. Bocquet, M.T. Pope, A.F. Williams, 182Tungsten Mössbauer spectroscopy of heteropolytungstates, Dalton Trans. 2009, 5127-5131.

- J.L. Débieux, C.G. Bochet, Preparation of photoactivable amino acid derivatives, J. Org. Chem. 2009, 74, 4519-4524.

- C.G. Bochet, A. Blanc, Photolabile protecting groups in organic synthesis, in Handbook of preparative photochemistry, Angelo Albini, Ed., John Wiley 2009, in press.

- F.L. Stefanato, E. Abou-Mansour, A. Buchala, M. Kretschmer, A. Mosbach, M. Hahn, C.G. Bochet, J-P. Métraux, H.J. Schoonbeek, The ABC-transporter BcatrB protects Botrytis cinerea against camalexin and is a virulence factor on Arabidopsis thaliana, The Plant Journal 2009, 58(3), 499-510.

- S. Mercier, C.G. Bochet, Photolabile linkers units, in Linker Strategies in Solid-Phase Organic Synthesis, Peter Scott, Ed., John Wiley 2009.

- U. Streit, C.G. Bochet, Recent advances in arene photocycloadditions, Chimia 2008, 62, 962-966.

- F. Birbaum, A. Neels, C.G. Bochet, The photochemistry of allenyl salicylaldehydes, Org. Lett. 2008, 10, 3175-3178.

-    J. Haesler, I. Schindelholz, E. Riguet, C.G. Bochet, W. Hug, Absolute Configuration of Chirally Deuterated Neopentane, Nature 2007, 446 , 526-529.

-    E. Riguet, C.G. Bochet, A new safety-catch photolabile protecting group, Org. Lett. 2007 , 9 , 5453-5456.

-    C.-L. Ciana, C.G. Bochet, Clean and Easy Photochemistry, Chimia 2007 , 650-654 .

-    J.L. Débieux, A. Cosandey, C. Helgen, C.G. Bochet, Photoacylation of alcohols in neutral medium, Eur. J. Org. Chem . 2007, 2073-2077.

-    A. Blanc, C.G. Bochet, Isotope Effects in Photochemistry. 2. Application to Chromatic Orthogonality , Organic Letters 2007, 9 , 2649-2651.

-    C. Helgen, C.G. Bochet, Photoacylation of amines with new heterocycles, Heterocycles 2006 , 67(2) , 797-805.

-    C.G. Bochet, Photochemical release of various functional groups, Pure & Appl. Chem. 2006 , 78(2) , 241-247.

-    J. Lage Robles, C.G. Bochet, Photochemical liberation of aldehydes, Org. Lett. 2005 , 7 , 3545-3547.

-    A.D. Cohen, C. Helgen, C.G. Bochet, J.P. Toscano, The Mechanism of Photoinduced Acylation of Amines by N-Acyl-5,7-dinitroindoline as Determined by TRIR Spectroscopy, Org. Lett. 2005 , 7 , 2845-2847.

-    V. Tamilmani, C.A. Daul, J. Lage Robles, C.G. Bochet, P. Venuvanalingam, Hydrogen Bond Stabilization in Diels-Alder Transition States. The Cycloaddition of hydroxy-ortho-quinodimethane with Fumaric acid and Dimethylfumarate. Chem. Phys. Lett. 2005 , 406 , 355-359 .

-    C.G. Bochet, Photochemical activation of functional groups, in Advances in Organic Synthesis, G. Jenner, Ed., 2005 , 1 , 3-23.

-    V. Fluxa, T.A. Jenny, C.G. Bochet, Determination of tetrasubstituted alkene geometry by proton NMR, Tetrahedron Lett. 2005 , 46 , 3793-3795.

-    C.G. Bochet, Chromatic orthogonality in organic synthesis, Synlett 2004 , 2268-2274.

-    A. Blanc, C.G. Bochet, Isotope Effects in Photochemistry. 1. o -Nitrobenzyl alcohol derivatives, J. Am. Chem. Soc., 2004 , 126 , 7174-7175.

-    M. Kessler, R. Glatthar, B. Giese, C.G. Bochet, Orthogonal Photocleavable Protecting Groups in Solid Phase Synthesis, Org. Lett. 2003 , 5 , 1179-1181.

-    A. Blanc, C.G. Bochet, Bis-(o-nitrophenyl)-ethanediol: a practical photolabile protecting group for ketones and aldehydes, J. Org. Chem, 2003 , 68 , 1138-1141.

-    K.M. Fromm, E.D. Gueneau, H. Goesmann, C.G. Bochet, One-dimensional water" and "one-dimensional acid" as new proton conducting material in analogy to biological water channels? Synthesis and the unique crystal structure of 1 ? [(H 2 O) Ì (DB18C6)( m 2 -H 2 O) 2/2 ] 1 ? [(H 3 O) Ì (DB18C6)( m 2 -H 2 O) 2/2 ]I 3 (DB18C6 = dibenzo-18-crown-6), Z. Anorg. Allg. Chem. 2003 ,629 , 597-600 .

-    C. Helgen, C.G. Bochet, Photochemical Protection of Amines with the Cbz Group, J. Org. Chem, 2003 , 68 , 2483-2486 .

-    A. Blanc, C.G. Bochet, Wavelength-controlled orthogonal photolysis of protecting groups, J. Org. Chem, 2002 , 67 , 5567-5577.

-    C.G. Bochet, Photolabile protecting groups and linkers, J. Chem. Soc., Perkin Trans. I 2002 , 125-152 .

-    C. Helgen, C.G. Bochet, Preparation of Secondary and Tertiary Amides under Neutral Conditions by Photochemical Acylation of Amines, Synlett 2001 , 1968-1970.

-    C.G. Bochet, Selective Synthesis, New Reagents for Specific Transformations, Champéry, June 6-9, 2001, Chimia 2001 , 55 , 732-736 .

-    C.G. Bochet, Orthogonal Photolysis of Protecting Groups. Angew. Chem. Int. Ed. Engl. 2001 , 40 , 2071-2073.

-    D. D'Addona, C.G. Bochet, Preparation of carbamates from alcohols and amines under mild conditions, Tetrahedron Lett. 2001 , 42, 5227-5229.

-    C.G. Bochet, Wavelength-selective Cleavage of Photolabile Protecting Groups. Tetrahedron Lett. 2000 , 41 , 6341-6346.

-    W. Oppolzer, C.G. Bochet, Asymmetric synthesis of the spirocyclic core of the Cylindricine-type alkaloids. Tetrahedron: Asymmetry 2000 , 11 , 4761-4770.

-    C. Edder, C. Piguet, G. Bernardinelli, J. Mareda, C.G. Bochet, J.C.G. Bünzli, G. Hopfgartner, Control of Thermodynamic Selectivity and Fine Tuning of Iron(II) Spin-crossover Equilibria in Self-assembled Non-covalent Heterodimetallic d-f Podates: Unusual Electronic Effects of Electro-withdrawing Sulfonamide Groups. Inorg. Chem, 2000 , 39 , 5059-5073 .

-    C. G. Bochet, 35th ESF/EUCHEM Conference on Stereochemistry, Chimia 2000 , 54 , 472-477.

-    B.M. Trost, T.L. Calkins, C.G. Bochet, A concise convergent synthesis of (+)-Parviflorin, (+)-Squamocin K and (+)-5 S -hydroxyparviflorin. Angew. Chem. Int. Ed. Engl. 1997 , 36 , 2632-2635.

-    C.G. Bochet, Synthèse asymétrique d'alcaloïdes par hydroxyamination électrophile d'énolates chiraux. Première synthèse totale de la (+)-Trianthine. Université de Genève, Thèse N° 2836, 1996 .

-    W. Oppolzer, C.G. Bochet, Enantioselective Preparation and Hydroboration of Cyclic Enamides: Synthesis of (2S)-Pseudoconhydrine, Tetrahedron Lett. 1995 , 36 , 2959-2962.

-    C. Piguet, J.C.G. Bünzli, G. Bernardinelli, C.G. Bochet, P. Froidevaux, Design of Luminescent Building Blocks for Supramolecular Triple-Helical Lanthanide Complexes, J. Chem. Soc., Dalton Trans. 1995 , 83-97.

-    W. Oppolzer, C.G. Bochet, E. Merifield, Diastereo- and Enantioselective Syntheses of (-)-Coniine, (-)-Solenopsin A, (-)-Solenopsis fugax venom and (-)-Xenovenine via Deoxygenative Decarboxylation of 2-Carbonylsultam-Substituted N-Hydroxy-Piperidines and Pyrrolidines, Tetrahedron Letters 1994 , 35 , 7015-7018.

-    W. Oppolzer, A.C. Spivey, C.G. Bochet, Suprafaciality of Thermal N -4-Alkenylhydroxylamine Cyclizations: Syntheses of (±)- a -Lycorane and (+)-Trianthine, J. Am. Chem. Soc. 1994 , 116, 3139-3140.

-   C.G. Bochet, C. Piguet, A.F. Williams, Synthesis and Electronic Properties of Intensely Coloured Iron(II) Complexes with New 4-Substituted Planar Tridentate Nitrogen Ligands Analogous to 2,2':6',2"-Terpyridine, Helv. Chim. Acta 1993 , 76 , 372-384.

 
Updated on Oct 21, 2011