Department of
chemistry
Chemin du Musee 9
CH-1700 Fribourg
Switzerland
Tel.: +41-(0)26-300 8758
Fax: +41-(0)26-300 9738
christian.bochet (at) unifr.ch
Publications
-
T. Solomek, S. Mercier, T. Bally,
C.G. Bochet, Photolysis of ortho-nitrobenzylic derivatives: the
importance of
the leaving group, 2012, in press.
- J.L. Débieux, C.G. Bochet, The
all-photochemical synthesis of an OGP(10-14) precursor, Chem. Sci.2011,
in press.
- C.G. Bochet, A. Blanc,
Photolabile protecting groups in organic synthesis, in 2010 CRC
Handbook of
photochemistry and photobiology,
A.
Griesbeck, M. Oelgemoeller, Eds, Taylor and Francis 2011, in press.
- N. Charbonnet, E.
Riguet, C. G.
Bochet, Singlet oxygen-induced rearrangement of furan derivatives, Synlett, 2011,
2231-2233.
- V. San Miguel Arnanz, C. G. Bochet,
A. del Campo, Wavelength selective caged surfaces: how many functional
levels
are possible? J. Am. Chem. Soc. 2011,
133, 5380-5388.
- U. Streit, C. G. Bochet, The
arene-alkene photocycloaddition, Beilstein Journal of Organic
Chemistry, 2011, 7,
525-542.
- H. Haning, C.G. Mañas, V.
Paddock, C.G. Bochet, A.J.P. White, G. Bernardinelli, I. Mann, W.
Oppolzer,
A.C. Spivey, Total Synthesis of the Amaryllicaceae Alkaloid Clivonine, Org.
Biomol.
Chem. 2011, 9, 2809-2820.
- T. Jack, J.
Simonin, S. Singhanat, C. G. Bochet,
“Unconventional Methods in Organic Synthesis”, 41th CUSO Summer School
in
Organic Chemistry. Chimia 2011, 65, 97-99.
- C.G. Mañas, V. Paddock, C.G.
Bochet, A.C. Spivey, A.J.P. White, I. Mann, W. Oppolzer, Total
Synthesis of the
Lycorenine-type Amaryllicaceae Alkaloid (+/-)-Clivonine via a
Biomimetic
Ring-switch from a Lycorine-type Progenitor, J. Am. Chem. Soc. 2010, 132, 5176-5178.
-
C.G. Bochet, Hard work
and light experience: early steps in photochemistry, Chimia2009,
63,
872-874
- C.G. Bochet, T. Draper,
B. Bocquet, M.T. Pope, A.F. Williams,
182Tungsten Mössbauer spectroscopy of heteropolytungstates, Dalton Trans. 2009, 5127-5131.
- J.L. Débieux, C.G. Bochet, Preparation of photoactivable amino
acid derivatives, J. Org. Chem.2009, 74, 4519-4524.
- C.G. Bochet, A. Blanc, Photolabile protecting groups in organic
synthesis, in Handbook of preparative photochemistry, Angelo Albini,
Ed., John Wiley 2009, in press.
- F.L. Stefanato, E. Abou-Mansour, A. Buchala, M. Kretschmer, A.
Mosbach, M. Hahn, C.G. Bochet, J-P. Métraux, H.J. Schoonbeek,
The ABC-transporter BcatrB protects Botrytis cinerea against camalexin
and is a virulence factor on Arabidopsis thaliana, The Plant Journal2009, 58(3), 499-510.
- S. Mercier, C.G. Bochet, Photolabile linkers units, in Linker
Strategies in Solid-Phase Organic Synthesis, Peter Scott, Ed., John
Wiley 2009.
- U. Streit, C.G. Bochet, Recent advances in arene photocycloadditions,
Chimia2008, 62, 962-966.
- F. Birbaum, A. Neels, C.G. Bochet, The photochemistry of allenyl
salicylaldehydes, Org. Lett. 2008,
10, 3175-3178.
-
J. Haesler, I. Schindelholz, E. Riguet, C.G. Bochet, W.
Hug, Absolute Configuration of Chirally Deuterated Neopentane, Nature
2007, 446
, 526-529.
- E. Riguet,
C.G. Bochet, A new safety-catch photolabile protecting group, Org.
Lett. 2007 , 9 , 5453-5456.
- J.L.
Débieux, A. Cosandey, C. Helgen, C.G. Bochet, Photoacylation of
alcohols in neutral medium, Eur. J. Org. Chem . 2007,
2073-2077.
- A. Blanc,
C.G. Bochet, Isotope Effects in Photochemistry. 2. Application to
Chromatic Orthogonality , Organic Letters 2007, 9
, 2649-2651.
- C. Helgen,
C.G. Bochet, Photoacylation of amines with new heterocycles, Heterocycles
2006 ,
67(2) , 797-805.
- C.G.
Bochet, Photochemical release of various functional groups, Pure
& Appl. Chem. 2006 , 78(2)
, 241-247.
- J. Lage
Robles, C.G. Bochet, Photochemical liberation of aldehydes, Org.
Lett. 2005 , 7 , 3545-3547.
-
A.D. Cohen, C. Helgen, C.G. Bochet, J.P. Toscano, The
Mechanism of Photoinduced Acylation of Amines by
N-Acyl-5,7-dinitroindoline as Determined by TRIR Spectroscopy, Org.
Lett. 2005 , 7 , 2845-2847.
-
V. Tamilmani, C.A. Daul, J. Lage Robles, C.G. Bochet, P.
Venuvanalingam, Hydrogen Bond Stabilization in Diels-Alder Transition
States. The Cycloaddition of hydroxy-ortho-quinodimethane with Fumaric
acid and Dimethylfumarate. Chem. Phys. Lett. 2005 ,
406 , 355-359 .
- C.G.
Bochet, Photochemical activation of functional groups, in Advances
in Organic Synthesis, G. Jenner, Ed., 2005 , 1
, 3-23.
- V. Fluxa,
T.A. Jenny, C.G. Bochet, Determination of tetrasubstituted alkene
geometry by proton NMR, Tetrahedron Lett. 2005 ,
46 , 3793-3795.
- A. Blanc,
C.G. Bochet, Isotope Effects in Photochemistry. 1. o -Nitrobenzyl
alcohol derivatives, J. Am. Chem. Soc., 2004 ,
126 , 7174-7175.
-
M. Kessler, R. Glatthar, B. Giese, C.G. Bochet, Orthogonal
Photocleavable Protecting Groups in Solid Phase Synthesis, Org.
Lett. 2003 , 5 , 1179-1181.
-
A. Blanc, C.G. Bochet, Bis-(o-nitrophenyl)-ethanediol: a
practical photolabile protecting group for ketones and aldehydes, J.
Org. Chem, 2003 , 68 , 1138-1141.
-
K.M. Fromm, E.D. Gueneau, H. Goesmann, C.G. Bochet,
One-dimensional water" and "one-dimensional acid" as new proton
conducting material in analogy to biological water channels? Synthesis
and the unique crystal structure of 1 ? [(H 2 O) Ì (DB18C6)( m 2
-H 2 O) 2/2 ] 1 ? [(H 3 O) Ì (DB18C6)( m 2 -H 2 O) 2/2 ]I 3
(DB18C6 = dibenzo-18-crown-6), Z. Anorg. Allg. Chem. 2003
,629 ,
597-600 .
- C. Helgen,
C.G. Bochet, Photochemical Protection of Amines with the Cbz Group, J.
Org. Chem, 2003 , 68 , 2483-2486 .
- A. Blanc,
C.G. Bochet, Wavelength-controlled orthogonal photolysis of protecting
groups, J. Org. Chem, 2002 , 67 ,
5567-5577.
- C.G.
Bochet, Photolabile protecting groups and linkers, J. Chem. Soc., Perkin
Trans. I 2002 , 125-152 .
-
C. Helgen, C.G. Bochet, Preparation of Secondary and
Tertiary Amides under Neutral Conditions by Photochemical Acylation of
Amines, Synlett 2001 , 1968-1970.
- C.G.
Bochet, Selective Synthesis, New Reagents for Specific Transformations,
Champéry, June 6-9, 2001, Chimia 2001 ,
55 , 732-736 .
- D.
D'Addona, C.G. Bochet, Preparation of carbamates from alcohols and
amines under mild conditions, Tetrahedron Lett. 2001
, 42, 5227-5229.
- C.G.
Bochet, Wavelength-selective Cleavage of Photolabile Protecting Groups.
Tetrahedron Lett. 2000
, 41 ,
6341-6346.
- W.
Oppolzer, C.G. Bochet, Asymmetric synthesis of the spirocyclic core of
the Cylindricine-type alkaloids. Tetrahedron: Asymmetry 2000
, 11 ,
4761-4770.
-
C. Edder, C. Piguet, G. Bernardinelli, J. Mareda, C.G.
Bochet, J.C.G. Bünzli, G. Hopfgartner, Control of Thermodynamic
Selectivity and Fine Tuning of Iron(II) Spin-crossover Equilibria in
Self-assembled Non-covalent Heterodimetallic d-f Podates: Unusual
Electronic Effects of Electro-withdrawing Sulfonamide Groups. Inorg.
Chem, 2000 , 39 , 5059-5073 .
- C. G.
Bochet, 35th ESF/EUCHEM Conference on Stereochemistry, Chimia 2000
, 54 ,
472-477.
-
B.M. Trost, T.L. Calkins, C.G. Bochet, A concise
convergent synthesis of (+)-Parviflorin, (+)-Squamocin K and (+)-5 S
-hydroxyparviflorin. Angew.
Chem. Int. Ed. Engl. 1997 , 36 ,
2632-2635.
-
C.G. Bochet, Synthèse asymétrique
d'alcaloïdes par hydroxyamination électrophile
d'énolates chiraux. Première synthèse totale de la
(+)-Trianthine. Université de Genève, Thèse
N° 2836, 1996 .
-
W. Oppolzer, C.G. Bochet, Enantioselective Preparation and
Hydroboration of Cyclic Enamides: Synthesis of (2S)-Pseudoconhydrine, Tetrahedron
Lett. 1995 , 36 , 2959-2962.
-
C. Piguet, J.C.G. Bünzli, G. Bernardinelli, C.G.
Bochet, P. Froidevaux, Design of Luminescent Building Blocks for
Supramolecular Triple-Helical Lanthanide Complexes, J. Chem.
Soc., Dalton Trans. 1995 , 83-97.
-
W. Oppolzer, C.G. Bochet, E. Merifield, Diastereo- and
Enantioselective Syntheses of (-)-Coniine, (-)-Solenopsin A,
(-)-Solenopsis fugax venom and (-)-Xenovenine via Deoxygenative
Decarboxylation of 2-Carbonylsultam-Substituted N-Hydroxy-Piperidines
and Pyrrolidines, Tetrahedron Letters 1994 ,
35 , 7015-7018.
- W.
Oppolzer, A.C. Spivey, C.G. Bochet, Suprafaciality of Thermal N -4-Alkenylhydroxylamine
Cyclizations: Syntheses of (±)- a -Lycorane and (+)-Trianthine, J.
Am. Chem. Soc. 1994 , 116,
3139-3140.
-
C.G. Bochet, C. Piguet, A.F. Williams, Synthesis and Electronic
Properties of Intensely Coloured Iron(II) Complexes with New
4-Substituted Planar Tridentate Nitrogen Ligands Analogous to
2,2':6',2"-Terpyridine, Helv. Chim. Acta 1993 ,
76 , 372-384.